I wouldn't worry too much... you've made your bed now. Looking on the bright side VAGs are a lot less needy than a lot of other brands (in particular Toyota) when it comes to routine servicing. However, you'll probably ignore spec and do as much as you would to a Toyota anyway. That's not something I would necessarily criticise, particularly when you're trying to make it last twice as long as I would expect at the outside judging by your C5 kilometreage.
Essentially, there's three big ticket items - the clutch/flywheel, the timing belt and the DPF... so let's look at each of those in a bit more detail.
Going back to the MKI and MKII, taximen typically expected the clutch/flywheel to last 150k. Mine went more or less exactly at that point and when Stuart took it in he said Sachs out, Sachs in, you'll be good for another 150k. Strangely though (I took it apart last weekend on account of a gearbox issue) he put a Luk clutch in rather than the Sachs he suggested. Whether he took a Luk out or not I don't know but I guess I was lucky a Luk went in 'cos it lasted 250k - in fact is still working but will be replaced with a solid flywheel conversion on account of the gearbox issue. Anyway, I read on one or more fora that VAG use two makes of clutch/flywheel, Sachs and Luk and, of the two, Luk is considered to be superior. Maybe you are lucky enough to have a Luk in yours and/or, perhaps less likely, the durability of both have improved over the years.
Manufacturer spec for timing belt replacement for the MKIII is 210,000 kilos. However, I got a noise from the tensioner (not particularly unusual and definitely a prompt for action) around 192,000 kilos so had it replaced by Aiden in Balrothery for €330. Some say it should be done after 5 or 7 years but the manual doesn't specify a time limit for it at all. Anywaysanall, ifn you hear the tensioner (sounds like a belt flapping rather than a bearing) get it done. Reducing intervals to 160,000 would probably be prudent... that's what the spec is for the MKI and MKII.
DPF replacements aren't particular to VAGs by any means. In fact, it was Ken's Toyota DPF saga that first made me research my own DPF a bit. I've bought cars for less than it ended up costing Ken! Autdoc sell replacements for mine for c.€350 - c.€550 depending on whether you want the single canister (DPF only) or the two canisters (DPF & Cat). At that rate it's hardly worth cleaning unless it needs cleaning to get it out of limp mode (assuming it goes into limp mode) for the week it'll take to come from Poland! Anywaysanall, I don't think my yoke will get to the predicted expiration of 320,000 kilos if the EV grants are still around in 2026. However, there is an option to reset the Ash level in OBD Eleven that I'd obviously try before replacing the part(s) should I get to that kilometreage.
I've done a couple of screenshots from the VAG DPF app and OBD Eleven (below) to give you some idea of what you can expect from them. I've also included a couple of relevant links that you might find interesting. One of those suggests periodic cleaning (as you done on your C5) extends intervals between regens which would save fuel as during an active regen the car injects diesel on the exhaust stroke as well as the compression stroke to get the DPF/Exhaust burning.
Just a minor aside... in my last post on DPF soot/ash levels I mixed up the soot and ash. It's the ash that congeals and eventually kills the DPF not the soot!
VAG DPF app screenshot:

OBD Eleven Screenshot:

Buying a VAG DPF compatible device (the brother managed to buy one that wasn't compatible)
https://www.hypermiler.co.uk/dpf-diesel-particulate-filter/vag-dpf-vw-which-obd2-ii-elm327-dongle-should-i-use-bluetooth-wifiDPF discussion... Clutch/flywheel gets a mention too!
https://www.yetiownersclub.co.uk/threads/understanding-vag-dpf-app.8227/